✦ LIBER ✦

ChemInform Abstract: Protodeboronation of Tertiary Boronic Esters: Asymmetric Synthesis of Tertiary Alkyl Stereogenic Centers.

✍ Scribed by Stefan Nave; Ravindra P. Sonawane; Tim G. Elford; Varinder K. Aggarwal

Publisher: John Wiley and Sons
Year: 2011
Weight: 53 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201119024

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Tertiary boronic esters smoothly undergo protodeboronation in the presence of CsF or TBAF in aqueous solution.

📜 SIMILAR VOLUMES

ChemInform Abstract: Enantioselective Co

ChemInform Abstract: Enantioselective Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters: Methodology and Applications.

✍ Ravindra P. Sonawane; Vishal Jheengut; Constantinos Rabalakos; Robin Larouche-Ga 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 41 KB

## Abstract Tertiary boronic esters are successfully converted into the homologated alcohols (III) under standard Matteson conditions with complete retention of configuration.

Enantioselective Construction of Quatern

Enantioselective Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters: Methodology and Applications

✍ Dr. Ravindra P. Sonawane; Dr. Vishal Jheengut; Dr. Constantinos Rabalakos; Dr. R 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 317 KB

Enantioselective Construction of Quatern

Enantioselective Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters: Methodology and Applications

✍ Dr. Ravindra P. Sonawane; Dr. Vishal Jheengut; Dr. Constantinos Rabalakos; Dr. R 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 328 KB

ChemInform Abstract: Synthesis of Tertia

ChemInform Abstract: Synthesis of Tertiary Alkyl Fluoride Centers by Asymmetric C—C(F) Bond Formation.

✍ A. G. MYERS; L. MCKINSTRY; J. L. GLEASON 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

ChemInform Abstract: Highly Stereoselect

ChemInform Abstract: Highly Stereoselective Preparation of Tertiary Homoallylic Alcohols with Multiple Stereogenic Centers.

✍ Takeshi Takeda; Takuya Nishimura; Yasutaka Yatsumonji; Keiichi Noguchi; Akira Ts 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 89 KB 👁 1 views

ChemInform Abstract: Asymmetric Synthesi

ChemInform Abstract: Asymmetric Synthesis of Tertiary Benzylic Alcohols.

✍ Monika I. Antczak; Feng Cai; Joseph M. Ready 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 64 KB

## Abstract Vinyl, aryl, and alkynyl organometallics add to ketones containing a stereogenic sulfoxide to give tertiary alcohols in diastereo‐ and enantiomerically pure form such as (III) or (VII).