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ChemInform Abstract: Proline-Catalyzed Direct Inverse Electron Demand Diels—Alder Reactions of Ketones with 1,2,4,5-Tetrazines.

✍ Scribed by Hexin Xie; Liansuo Zu; Hanine R. Oueis; Hao Li; Jian Wang; Wei Wang

Publisher
John Wiley and Sons
Year
2008
Weight
44 KB
Volume
39
Category
Article
ISSN
0931-7597

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Inverse Electron Demand Diels-Alder Reactions of 3,6-Dichloro-[1,2,4,5]tetrazine. -Tetrazine (I) is used as an azadiene equivalent for inverse electron demand Diels -Alder reactions with alkynes and alkenes to give functionalized dichloropyridazines, e.g. (III), (V), and (VII). -(SPAREY, T.