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ChemInform Abstract: Preparation of α-Heteroatom Substituted Allylic Alcohols by Reaction of (E)-α-Selanylvinylzirconiums or (E)-α-Trimethylsilylvinylzirconiums with Aldehydes.

✍ Scribed by Xian Huang; Ai-Ming Sun

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Allylindium reagents, prepared from excess allylic halide (Br or I) and indium metal, react with α,β-unsaturated ketones and aldehydes to give, after aerobic acidic workup, homoallyl-substituted vinylcyclopropanes. This process was explored and developed after a chance discovery arising from a side