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ChemInform Abstract: Preparation of the First Tricoordinate Silyl Cation

โœ Scribed by Joseph B. Lambert; Yan Zhao; S. Mark Zhang

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis and Appli
ChemInform Abstract: Synthesis and Application of the First Chiral and Highly Lewis Acidic Silyl Cationic Catalyst.
โœ M. JOHANNSEN; K. A. JOERGENSEN; G. HELMCHEN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 1 views

Synthesis and Application of the First Chiral and Highly Lewis Acidic Silyl Cationic Catalyst. -Cationic silyl compounds containing a chiral dimethylbinaphthyl backbone are synthesized and used as highly active Lewis acid catalysts for (hetero) Diels-Alder reactions with modest enantioselectivity.