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ChemInform Abstract: Preparation of Methyl 4,6-Di-O-acetyl-3-C-nitro-2-enopyranoside Derivatives and Their Reduction with Sodium Borodeuteride.

โœ Scribed by A. SETA; K. TOKUDA; M. KAIWA; T. SAKAKIBARA


Book ID
112032792
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Preparation of methyl 4,6-di-O-acetyl-3-
โœ Akinori Seta; Kiohisa Tokuda; Miki Kaiwa; Tohru Sakakibara ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 755 KB

The conformationally flexible title compounds were prepared and subjected to reduction with sodium borodeuteride. Deuteride ion attacks exclusively from the side opposite of the anomeric methoxyl group. However, the stereoselectivity of a similar reduction of the corresponding 4,6-O-benzylidene-~-I>