Treatment of 4,6-diacetate 3 with tert-butyl hydroperoxide gave the Sr~2' product 6 in high yield, the formation of which presumeably involves an intermediary nitronate. The thus prepared 6 reacted with nucleophiles to afford 2,3-anhydro derivatives having the talo configuration.
✦ LIBER ✦
ChemInform Abstract: Preparation of a Methyl 3,4-Dideoxy-3-C-nitro-α-D-threo-hex-3- enopyranoside Bearing a Peroxy Function at C-2 and Its Reactions with Some Nucleophiles.
✍ Scribed by A. SETA; K. TOKUDA; T. SAKAKIBARA
- Book ID
- 112023467
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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