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ChemInform Abstract: Preparation of Germyl-Substituted Dizinciomethanes and Their Reactions with Electrophiles.

โœ Scribed by Seijiro Matsubara; Hideaki Yoshino; Kiitiro Utimoto; Koichiro Oshima

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Preparation of Sily
ChemInform Abstract: Preparation of Silyl-Substituted Dizinciomethanes and Their Reactions with Electrophiles.
โœ Seijiro Matsubara; Yasuyuki Otake; Takuya Morikawa; Kiitiro Utimoto ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB

Preparation of Silyl-Substituted Dizinciomethanes and Their Reactions with Electrophiles. -Silylated dibromomethanes (I) react with finely divided zinc in the presence of catalytic amounts of PbCl 2 to give the corresponding dizincio compounds (II). These can be subjected to stepwise reactions with