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ChemInform Abstract: Preparation of Deoxygenated Derivatives of Neoanisatin, a Neurotoxic Sesquiterpenoid Having a β-Lactone.

✍ Scribed by Kazuyoshi Obitsu; Shojiro Maki; Takashi Hirano; Haruki Niwa

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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Synthesis of (−)-noranisatin, an oxidati
Synthesis of (−)-noranisatin, an oxidation product of a neurotoxic sesquiterpenoid anisatin having a novel spiro β-lactone
✍ Haruki Niwa; Shigeki Ito; Takashi Hasegawa; Kazumasa Wakamatsu; Tatsuya Mori; Ki 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 128 KB

The synthesis of (-)-noranisatin (2), an oxidation product of anisatin (1) possessing a novel Spiro P-lactone,was achieved starting from trio1 5 prepared from (R)-(+)-pulegone (3). Anisatin (1) is a neurotoxic sesquiterpenoid isolated from the seeds of Japanese star anise (Illicium anisurum L., shi