ChemInform Abstract: Preparation and Structural Characterization of RuII-DMSO and RuIII-DMSO-Substituted α-Keggin-Type Phosphotungstates, [PW11O39RuIIDMSO]5- and [PW11O39RuIIIDMSO]4-, and Catalytic Activity for Water Oxidation.

Microwave-Assisted Rapid Incorporation o

Microwave-Assisted Rapid Incorporation of Ruthenium into Lacunary Keggin-Type Polyoxotungstates: One-Step Synthesis, 99Ru, 183W NMR Characterization and Catalytic Activity of [PW11O39RuII(DMSO)]5–

✍ Alessandro Bagno; Marcella Bonchio; Andrea Sartorel; Gianfranco Scorrano 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 233 KB

Microwave irradiation for 15 minutes allowed the highly stable oxidation catalyst [PW 11 O 39 Ru II (DMSO)] 5-, as confirmed by 1 H, 31 P, 99 Ru and 183 W NMR techniques. selective hydrothermal synthesis of the diamagnetic, airgeometries of both 2 and 3 obtained with PM3(tm) semiem- [a