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ChemInform Abstract: Preparation and Crystal Structure of Na2Sn2Se5 — A Novel Chalcogenostannate(IV) with Layered Complex Anions.

✍ Scribed by Kurt O. Klepp; Markus Hainz

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Dimeric and Polymer
ChemInform Abstract: Dimeric and Polymeric Pnictidostannate(IV) Anions — Preparation and Crystal Structures of Na2K3[SnP3], Na2Cs3[SnP3] and Na2K3[SnBi3].
✍ M. ASBRAND; B. EISENMANN; H. ENGELHARDT; U. ROESSLER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

The title compounds are prepared from melts of mixtures of the elements. The isotypic [SnP 3 ] compounds crystallize in the orthorhombic system (space group Cmca, Z = 8) as determined by single crystal XRD, and contain dimeric [Sn 2 P 6 ] 10-anions formed by edge-sharing of two SnP 4 tetrahedra. Na