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ChemInform Abstract: Practical Preparation and Reactivity of Valuable Functionalized Cyclic α,α′-Ketodiesters.

✍ Scribed by T. LAVOISIER-GALLO; J. RODRIGUEZ

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Practical Preparation and Reactivity of Valuable Functionalized Cyclic α,α'-Ketodiesters. -The base-mediated condensation of dimethyl 3-oxoglutarate (I) with bishalomethyl derivatives (II), (IV), (VII), (IX) gives cyclic ketodiesters (III), (V), (VIII), and (X), respectively. Further reaction of these ketodiesters with bishalomethyl derivatives under similar conditions provides bicyclic ketodiesters [cf. (XI)]. -(LAVOISIER-GALLO, T.; RO-

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