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ChemInform Abstract: Practical Asymmetric Synthesis of Both Enantiomers of 6-(Hydroxymethyl)piperidin-2-one.

✍ Scribed by T. J. HODGKINSON; M. SHIPMAN

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Practical Asymmetric Synthesis of Both Enantiomers of 6-(Hydroxymethyl)piperidin-2-one.

-A practical route to both enantiomers of the title piperidine (VII), precursors for the synthesis of azinomycin analogues, based on the asymmetric dihydroxylation of alkenyl ester (I) using (DHQ) 2 AQN or the pseudo-enantiomeric (DHQD) 2 AQN ligand is accomplished. -(HODGKINSON, T.

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