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ChemInform Abstract: Polyfluoro N-Aryloxaziridines. Synthesis and Thermal Rearrangement.

โœ Scribed by V. A. PETROV; D. D. DESMARTEAU


Book ID
112038572
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Thermal Rearrangeme
โœ Z. DASZKIEWICZ; A. DOMANSKI; J. B. KYZIOL ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 26 KB ๐Ÿ‘ 2 views

Thermal Rearrangement of Pyridylnitramines. -In contrast to their N-methyl analogues, which rearrange to form the corresponding methylamino-nitroamines in 74-90% yield, 2-substituted pyridine (I) rearranges into two regioisomers (II) and (III), 4-substituted pyridine (IV) is much less prone to rear