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ChemInform Abstract: Polycyclitols: Stereoselective Synthesis of Enantiopure Polyhydroxylated Hydrindans (Annulated Carbasugars.)

โœ Scribed by Goverdhan Mehta; D. Srinivasa Reddy


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Tra
โœ M. TOYOTA; T. ASOH; M. MATSUURA; K. FUKUMOTO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 1 views

Stereoselective Transformation of Enantiopure Cyclohexenol into cis-Hydrindan. An Enantioselective Formal Total Synthetic Route to (+)-Pumiliotoxin C. -Starting from the known chiral acid (I) the biologically interesting title compound (IX) is synthesized. Key step in this approach is the cyclizatio