Enantioselective Copper-Catalyzed 1,4-Addition of Organozinc Reagents to Enones Using Chiral Oxazoline-Phosphite Ligands. -The enantioselective 1,4-addition of organozinc reagents to Ξ±,Ξ²-unsaturated ketones in the presence of chiral P,N-ligands (I) with a binaphthyl phosphite group and an oxazoline
ChemInform Abstract: Planar-Chiral Heterocycles as Ligands in Metal-Catalyzed Processes: Enantioselective Addition of Organozinc Reagents to Aldehydes.
β Scribed by P. I. DOSA; J. C. RUBLE; G. C. FU
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Ethyl Nipecotate-Derived New Chiral Ligand. -In order to compare the chirality induction of chiral Ξ²-and Ξ³-amino alcohols, chiral Ξ³-amino alcohol DMM is synthesized and tested as catalyst in the addition of Et 2 Zn to various aldehyd
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