✍ Scribed by S. KOHMOTO; H. YAJIMA; S. TAKAMI; K. KISHIKAWA; M. YAMAMOTO; K. YAMADA
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📜 SIMILAR VOLUMES
Mechanism of the Rearrangement of 7-Vinylnorcaradienes. -Thermal rearrangement of the diastereomeric 7-vinylnorcaradienes (I) and (II) provides three products, two formed via a 1,3-and 3,5-vinylcyclopropanecyclopentane rearrangement and the third one resulting from a 3,3-cope rearrangement.
An efficient and resuble copper on iron catalyst has been prepared for the cleavage of the carbon-carbon s-bond in a-aminocarbonyl compounds leading to the corresponding formylamides and acids with a maximal TON of up to 51,000. It is noteworthy that the copper on iron catalyst can be easily separat
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