ChemInform Abstract: Photochemical Reaction of ortho-Formylbenzyltrialkylstannanes for the Generation of α-Oxy-o-quinodimethane.
✍ Scribed by Hiroshi Sano; Daisuke Asanuma; Masanori Kosugi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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The Generation of α-Trimethylsiloxy-o-quinodimethanes Induced by One-Electron Reduction to o-Acylbenzyltributylstannanes. o-Quinodimethane intermediates, generated from (I) or (VI) are trapped with dienophiles (II) to give the corresponding cycloadducts. The isolation of the open-chain adduct (XII)
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