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ChemInform Abstract: Phosphoramidite Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of 3,4-Substituted Pyrrolidines.

✍ Scribed by Ana Z. Gonzalez; Diego Benitez; Ekaterina Tkatchouk; William A. III Goddard; F. Dean Toste


Publisher
John Wiley and Sons
Year
2011
Weight
65 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Gold(I)-Catalyzed E
✍ Alberto Martinez; Patricia Garcia-Garcia; Manuel A. Fernandez-Rodriguez; Felix R 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 58 KB 👁 1 views

## Abstract Au/Ag‐Catalyzed cycloisomerization of a variety of o‐alkynylstyrene derivatives, e.g. (I) and (VII), proceeds with moderate to high enantioselectivity (up to 92% e.e.) in the presence of an axially chiral MeO‐biphep ligand to give alkenyl‐substituted indenes (II) and (VIII), resp., in h