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ChemInform Abstract: Phosphane-Catalyzed Umpolung Addition Reaction of Nucleophiles to Ethyl 2-Methyl-2,3-butadienoate.

✍ Scribed by Xiao-Yang Guan; Yin Wei; Min Shi

Publisher: John Wiley and Sons
Year: 2011
Weight: 50 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201132021

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✦ Synopsis

Abstract

Oxygen, nitrogen, and carbon nucleophiles give with dienoate (II) under phosphane catalysis the corresponding umpolung addition products with high (E)‐selectivities.

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