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ChemInform Abstract: Beyond the Aza-Morita—Baylis—Hillman Reaction: Lewis Base Catalyzed Reactions of N-Boc-imines with Ethyl 2,3-Butadienoate.

✍ Scribed by Xiao-Yang Guan; Yin Wei; Min Shi


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
41
Category
Article
ISSN
0931-7597

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## Abstract A series of polyether dendritic chiral phosphine Lewis bases was synthesized, and successfully applied to the asymmetric aza‐Morita–Baylis–Hillman reaction of __N__‐sulfonated imines (__N__‐arylmethylidene‐4‐methylbenzenesulfonamides) with methyl vinyl ketone (MVK), ethyl vinyl ketone (