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ChemInform Abstract: PhCh=P(MeNCH2CH2)3N: A Novel Ylide for Quantitative E Selectivity in the Wittig Reaction.

✍ Scribed by Zhigang Wang; Guangtao Zhang; Ilia Guzei; John G. Verkade


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: P(MeNCH2CH2)3N: An
✍ Zhigang Wang; John G. Verkade πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 2 views

P(MeNCH 2 CH 2 ) 3 N: An Efficient Nonionic Superbase for Wittig and Wittig-Horner Reactions. -The strong non-ionic title base effectively deprotonates triphenylphosphonium salts (I) and phosphonates (IV) under mild conditions. Reaction of the ylides generated with aldehydes provides an efficient a