ChemInform Abstract: Pd(0)-Catalyzed Coupling Reaction of Allyl N,N-Ditosylimide and Allyl N-Tosylamides as New Substrates for the Formation of π-Allylpalladium Complexes.

✍ Scribed by H. RHEE; D. YOON; S. KIM

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 36 KB
• Volume: 29
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199830076

✦ Synopsis

Pd(0)-Catalyzed Coupling Reaction of Allyl N,N-Ditosylimide and Allyl N-Tosylamides as New Substrates for the Formation of π-Allylpalladium Complexes. -Allylamides (I) undergo Pd(0)-catalyzed coupling reactions with C-, N-, and O-nucleophiles (II), (V), and (VIII) affording the expected monoallylated products (III), (VI), and (IX) together with minor amounts of diallylated compounds (IV) and (VII) in the case of Cand N-nucleophiles. -(RHEE, H.;