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ChemInform Abstract: Efficient Synthesis of Carbocyclic Nucleoside, (.+-.)-Homocarbovir via π-Allylpalladium Complex Formation from the Allyl N,N-Ditosylimide Substrate.

✍ Scribed by Hakjune Rhee; Dong-oh Yoon; Michael E. Jung


Publisher
John Wiley and Sons
Year
2000
Weight
37 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Pd(0)-Catalyzed Cou
✍ H. RHEE; D. YOON; S. KIM 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

Pd(0)-Catalyzed Coupling Reaction of Allyl N,N-Ditosylimide and Allyl N-Tosylamides as New Substrates for the Formation of π-Allylpalladium Complexes. -Allylamides (I) undergo Pd(0)-catalyzed coupling reactions with C-, N-, and O-nucleophiles (II), (V), and (VIII) affording the expected monoallylate