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ChemInform Abstract: Palladium(0)-Catalyzed Alkylative Cyclizations of Alkynes and Allenes Containing Electrophilic Functional Groups with Organoboron Reagents

✍ Scribed by Hirokazu Tsukamoto; Yoshinori Kondo

Publisher
John Wiley and Sons
Year
2010
Weight
15 KB
Volume
41
Category
Article
ISSN
0931-7597

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Palladium(0)-Catalyzed Coupling Cyclization of Functionalized Allenes with Hypervalent Iodonium Salts. -The title reaction of allenic alcohols and amines provides the corresponding heterocyclic compounds in good yields. Cyclization of allenic acids (IV) leads to formation of lactones (V), which are