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ChemInform Abstract: Palladium-Catalyzed Sequential Carboxylation-Alkoxycarbonylation of Acetylenic Amines.

โœ Scribed by A. BACCHI; G. P. CHIUSOLI; M. COSTA; B. GABRIELE; C. RIGHI; G. SALERNO

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Alkoxycarbonylation of Aryl-and Alkenyliodonium Salts. -While the Pd-catalyzed alkoxycarbonylation of hypervalent iodine tetrafluoroborates and tosylates, e.g. (I) and (V), gives the corresponding methyl and phenyl ester (IV) and (VI), resp., in good yields, the use of iodonium t