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ChemInform Abstract: Palladium-Catalyzed Intramolecular Coupling of Vinyl Halides and Ketone Enolates. Synthesis of Bridged Azabicyclic Compounds.

✍ Scribed by Daniel Sole; Emma Peidro; Josep Bonjoch

Publisher: John Wiley and Sons
Year: 2000
Weight: 31 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200045045

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✦ Synopsis

Abstract

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## Abstract Vinyl halides undergo intramolecular coupling with amino‐tethered ketones, esters, and nitriles in the presence of a palladium catalyst and potassium phenoxide as the base. This reaction constitutes a useful methodology for the synthesis of monocyclic, bridged, and spirocyclic nitrogen‐