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ChemInform Abstract: Palladium-Catalyzed Hydrostannylation of α-Heteroalkynes and Alkynyl Esters in Ionic Liquids.

✍ Scribed by Mingzhong Cai; Yongguang Wang; Wenyan Hao


Publisher
John Wiley and Sons
Year
2008
Weight
37 KB
Volume
39
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Hydrostannylation of
✍ Mingzhong Cai; Yongguang Wang; Wenyan Hao 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

## Abstract Palladium‐catalyzed hydrostannylation reactions of α‐heteroalkynes and alkynyl esters were achieved with high regio‐ and stereoselectively in the ionic liquid 1‐butyl‐3‐methylimidazolium hexafluorophosphate ([bmim][PF~6~]) at 60 °C in high yields. Our system not only avoids the use of h