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ChemInform Abstract: Palladium-Catalyzed Esterification of Aryl Halides Using Aryl Formates Without the Use of External Carbon Monoxide.

✍ Scribed by Fujihara, Tetsuaki; Hosoki, Tomoya; Katafuchi, Yuko; Iwai, Tomohiro; Terao, Jun; Tsuji, Yasushi

Book ID
118755157
Publisher
John Wiley and Sons
Year
2012
Weight
35 KB
Volume
43
Category
Article
ISSN
0931-7597

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Palladium-Catalyzed Hydroesterification
Palladium-Catalyzed Hydroesterification of Alkynes Employing Aryl Formates without the Use of External Carbon Monoxide
✍ Yuko Katafuchi; Tetsuaki Fujihara; Tomohiro Iwai; Jun Terao; Yasushi Tsuji πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 258 KB

## Abstract A highly efficient hydroesterification of alkynes employing aryl formates has been developed without the use of external carbon monoxide and at ambient pressure. The reaction in the presence of a palladium‐xantphos catalyst system selectively affords Ξ±,β‐unsaturated esters in good to hi