Palladium-Catalyzed Hydroesterification
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Yuko Katafuchi; Tetsuaki Fujihara; Tomohiro Iwai; Jun Terao; Yasushi Tsuji
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Article
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2011
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John Wiley and Sons
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English
β 258 KB
## Abstract A highly efficient hydroesterification of alkynes employing aryl formates has been developed without the use of external carbon monoxide and at ambient pressure. The reaction in the presence of a palladiumβxantphos catalyst system selectively affords Ξ±,Ξ²βunsaturated esters in good to hi