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ChemInform Abstract: Oxidative Dearomatization in the Synthesis of Erythrina, Oxindole and Hexahydropyrrolo[2,3-b]indole Skeletons.

✍ Scribed by Jixuan Liang; Jingbo Chen; Jianping Liu; Liang Li; Hongbin Zhang

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
41
Category
Article
ISSN
0931-7597

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Synthesis of the 3a-(3-Indolyl)-1,2,3,3a,8,8a-hexahydropyrrolo[2,3b]indole Core of Leptosins D-F. -The Fischer indole reaction of the previously reported L-tryptophan-derived aldehyde (I) with phenyl hydrazine in the presence of freshly fused zinc chloride provides the core unit (IV) of the leptosin