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ChemInform Abstract: Oxidative Coupling of Deltahedral [Ge9]4- Zintl Ions.

โœ Scribed by Li Xu; Slavi C. Sevov


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
31
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: Ge4-9: A Deltahedra
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Ge4-9: A Deltahedral Zintl Ion Now Made in the Solid State Reaction. -Rubyred semitransparent single crystals of Cs4Ge9 and of the isostructural Rb4Ge9 are prepared at 800 โ€ข C from a nonstoichiometric mixture of the elements and characterized by single-crystal XRD and magnetic measurements. The pur

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## Abstract Six new derivatized deltahedral Zintl ions have been synthesized by reactions between the known Zintl ions Ge~9~^__n__โˆ’^ with the halides R~3~EX and/or the corresponding anions R~3~E^โˆ’^ for E=Ge or Sn. This rational approach is based on our previous discovery that these derivatization r