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ChemInform Abstract: Overcoming Intrinsic Diastereoselection Using Polyleucine as a Chiral Epoxidation Catalyst.

โœ Scribed by Peter C. Ray; Stanley M. Roberts

Book ID
101879517
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES

Overcoming intrinsic diastereoselection
Overcoming intrinsic diastereoselection using polyleucine as a chiral epoxidation catalyst
โœ Peter C. Ray; Stanley M. Roberts ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 239 KB

The use of polyleucine in the diastereoselective, catalyst-controlled epoxidation of enantiomerically pure 7-heterosubstituted-ct,13-unsaturated ketones (1), to yield the corresponding ct,13-epoxy-)',8-(isopropylidene)dioxy carbonyl compounds, is described.