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ChemInform Abstract: Orthoester Claisen Rearrangement of a D-Glucose-Derived Spirocyclic Substrate.

✍ Scribed by Ken-ichi Takao; Hiroshi Saegusa; Kin-ichi Tadano

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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Enantioselective Synthesis of Ξ²-Substituted Butyric Acid Derivatives via Orthoester Claisen Rearrangement of Enzymatically Resolved Allylic Alcohols: Application to the Synthesis of (R)-(-)-Baclofen. -A three step synthesis of the GABA B receptor agonist (-)-baclofen is presented. Key step in this