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ChemInform Abstract: Organosamariums: Preparation Using Diiodosamarium and Reactivity in Tetrahydropyran.

✍ Scribed by B. HAMANN-GAUDINET; J.-L. NAMY; H. B. KAGAN

Book ID
101871121
Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Generation and reactivity of allylic and
Generation and reactivity of allylic and benzylic samarium compounds using diiodosamarium in tetrahydropyran
✍ BΓ©atrice Hamann-Gaudinet; Jean-Louis Namy; Henri B. Kagan πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 161 KB

Diiodosamariura prepared in THP reduces allylic iodides and bromides at 0 or -15 Β°(7 to give organosamarium compounds which are stable under these conditions. These allylic samarium compounds react with many functionalities including the keto group of keto esters. Benzylic samarium compounds were pr