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ChemInform Abstract: Generation and Reactivity of Allylic and Benzylic Samarium Compounds Using Diiodosamarium in Tetrahydropyran.

✍ Scribed by B. HAMANN-GAUDINET; J.-L. NAMY; H. B. KAGAN

Book ID
101856283
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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Generation and reactivity of allylic and
Generation and reactivity of allylic and benzylic samarium compounds using diiodosamarium in tetrahydropyran
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Diiodosamariura prepared in THP reduces allylic iodides and bromides at 0 or -15 Β°(7 to give organosamarium compounds which are stable under these conditions. These allylic samarium compounds react with many functionalities including the keto group of keto esters. Benzylic samarium compounds were pr

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v