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ChemInform Abstract: Organocatalyzed Cyclizations of π-Allylpalladium Complexes: A New Method for the Construction of Five- and Six-Membered Rings.

✍ Scribed by Filip Bihelovic; Radomir Matovic; Bojan Vulovic; Radomir N. Saicic


Publisher
John Wiley and Sons
Year
2008
Weight
54 KB
Volume
39
Category
Article
ISSN
0931-7597

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Strategy for the Construction of Functionalized Five-and Six-Membered Carbocycles. -Conjugate addition of the Grignard reagents (II) and (IV) to the nitro olefins (I) leads to the intermediate formation of nitronates, which are trapped as silyl nitronates and subsequently cyclized by intramolecular