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ChemInform Abstract: Organocatalytic Enantioselective Sulfenylation of β-Keto Phosphonates: A Convenient Approach to Construct Hetero-Quaternary Stereocenters.

✍ Scribed by Aijun Lin; Ling Fang; Xi Zhu; Chengjian Zhu; Yixiang Cheng


Publisher
John Wiley and Sons
Year
2011
Weight
31 KB
Volume
42
Category
Article
ISSN
0931-7597

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Organocatalytic Enantioselective Sulfeny
✍ Aijun Lin; Ling Fang; Xi Zhu; Chengjian Zhu; Yixiang Cheng 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

## Abstract The highly effective and enantioselective sulfenylation of β‐keto phosphonates catalyzed by α,α‐diaryl‐L‐prolinols has been developed. The optically active α‐sulfenylated β‐keto phosphonates could be obtained under mild reaction conditions in good yields (up to 92%) and with excellent e