ChemInform Abstract: Organocatalytic Enantioselective Friedel—Crafts Reactions of 1-Naphthols with Aldimines.
✍ Scribed by Guixia Liu; Shilei Zhang; Hao Li; Tangzhi Zhang; Wei Wang
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 37 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
The reaction is catalyzed best by the alkaloid‐derived bifunctional catalyst.
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## Abstract The bifunctional chiral thiourea—tertiary amine THU derived from cinchonine catalyzes the alkylation of sesamol and 2‐substituted derivatives with aromatic nitro olefins with up to 90% enantioselectivity.
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