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ChemInform Abstract: Organocatalytic Enantioselective Friedel—Crafts Alkylation of Sesamol with Nitro Olefins.

✍ Scribed by Hui Zhang; Yu-Hua Liao; Wei-Chen Yuan; Xiao-Mei Zhang

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The bifunctional chiral thiourea—tertiary amine THU derived from cinchonine catalyzes the alkylation of sesamol and 2‐substituted derivatives with aromatic nitro olefins with up to 90% enantioselectivity.

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