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ChemInform Abstract: Organocatalytic Asymmetric Vinylogous Addition to Quinones — Formation of Optically Active α-Aryl Ketones.

✍ Scribed by Jose Aleman; Christian Borch Jacobson; Kim Frisch; Jacob Overgaard; Karl Anker Joergensen


Publisher
John Wiley and Sons
Year
2008
Weight
44 KB
Volume
39
Category
Article
ISSN
0931-7597

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Manganese Catalyzed Asymmetric Oxidation of Alkanes to Optically Active Ketones Bearing Asymmetric Center at the α-Position. -Symmetrical alkanes (II) and (IV) are oxidized with iodosobenzene/4phenylpyridine-N-oxide in the presence of catalytic chiral (salen)Mn(III) complexes (I) providing optically