ChemInform Abstract: Optically Active Isoxazolidines and 1,3-Amino Alcohols by Asymmetric Selenocyclization Reactions of O-Allyl Oximes.
β Scribed by Marcello Tiecco; Lorenzo Testaferri; Francesca Marini; Silvia Sternativo; Claudio Santi; Luana Bagnoli; Andrea Temperini
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Asymmetric Reduction of Ketoxime Ethers to Optically Active O-Substituted Hydroxylamines with Reagents Prepared from Borane and Chiral Amino Alcohols. -The reduction in the presence of norephedrine is an efficient method to prepare chiral O-substituted hydroxylamines. However, O-Tbs and O-tBu subst