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ChemInform Abstract: One-Pot Synthesis of Diarylalkynes Using Palladium-Catalyzed Sonogashira Reaction and Decarboxylative Coupling of sp Carbon and sp2 Carbon.

✍ Scribed by Jeongju Moon; Miso Jeong; Hyungoog Nam; Jinhun Ju; Joong Ho Moon; Hyun Min Jung; Sunwoo Lee

Publisher: John Wiley and Sons
Year: 2008
Weight: 25 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200832095

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## Abstract Palladium‐catalyzed decarboxylative __sp‐sp__^2^ cross‐coupling reactions of aryl and vinyl halides and triflates with α,β‐ynoic acids using silver oxide have been developed. A variety of α,β‐ynoic acids were readily decarboxylated in the presence of silver oxide and then, generated __i