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ChemInform Abstract: One-Pot Synthesis of 5-Substituted 1H-Tetrazoles from Aryl Bromides with Potassium Hexakis(cyano-ϰC)ferrate(4—) (K4[Fe(CN)6]) as Cyanide Source.

✍ Scribed by Yizhong Zhu; Yiming Ren; Chun Cai

Publisher
John Wiley and Sons
Year
2009
Weight
23 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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One-Pot Synthesis of 5-Substituted 1H-Te
One-Pot Synthesis of 5-Substituted 1H-Tetrazoles from Aryl Bromides with Potassium Hexakis(cyano-κC)ferrate(4−) (K4[Fe(CN)6]) as Cyanide Source
✍ Yizhong Zhu; Yiming Ren; Chun Cai 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 German ⚖ 157 KB

A one-pot procedure for the synthesis of 5-substituted 1H-tetrazoles through the three-component reaction between an aryl bromide, potassium hexakis(cyano-kC)ferrate(4 À) (K 4 [Fe(CN) 6 ]) and NaN 3 catalyzed by [Pd(OAc) 2 ] and ZnBr 2 in the presence of 1,4-diazabicyclo[2.2.2]octane (dabco) was dev