ChemInform Abstract: One-Pot Generation and Conversion of Trichloroacetimidates for the Racemization-Free Allylation and Benzylation of α-Hydroxyesters and the Enantiopure Synthesis of a Chiral Diglycol.
✍ Scribed by Jens Christoffers; Ulrich Roessler
- Publisher
- John Wiley and Sons
- Year
- 2000
- Weight
- 32 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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A One Pot, Solvent-Free Synthesis of Acyclic α-Nitro Ketones Through the Nitroaldol Reaction. -Acyclic α-nitro ketones (III) (15 examples) are easily obtained in a one pot reaction in good yields through a solvent-free nitroaldol reaction of nitroalkanes (I) and aldehydes (II) on neutral alumina fo
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