The Ag(I)-promoted cyclization of 2.5~pentadiene-1,5diols containing both a ~tiary and a secondary or primary hydroxyl group, has been examined. In general, the reaction displays a preference for cyclixation through the more hindered tertiary hydroxyl group, sometimes to the exclusion of akernative
ChemInform Abstract: On the Chemoselectivity of Formation of 2-(α-Hydroxyalkyl)-2,5-dihydrofurans from Allenic Diols.
✍ Scribed by J. M. AURRECOECHEA; M. SOLAY
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
a-Allenic alcohols react rapidly with PhSeCl to produce derivatives of 3-phenylseleno-2,5-dihydrofuran in high yields. The synthesis of heterocycles via the electrophilically-induced cyclization of unsaturated acids,' alcohols, 2 and phenols with areneselenenyl halides or derivatives thereof4 has re
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Synthesis of Enantiomerically Enriched 2,5-Dihydrofuran Derivatives from Easily Available Enantiomerically Enriched 2-Butyne-1,4-diols by Stereospecific Transformation. -The enantiomerically enriched butynols (IV) and (X) are prepared by enantioselective reduction of keto alcohols (I) and (VII) wit