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ChemInform Abstract: Tandem Enzyme/Gold-Catalysis: From Racemic α-Allenic Acetates to Enantiomerically Enriched 2,5-Dihydrofurans in One-Pot.

✍ Scribed by Martta Asikainen; Norbert Krause

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
41
Category
Article
ISSN
0931-7597

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Abstract

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Tandem Enzyme/Gold-Catalysis: From Racem
Tandem Enzyme/Gold-Catalysis: From Racemic α-Allenic Acetates to Enantiomerically Enriched 2,5-Dihydrofurans in One Pot
✍ Martta Asikainen; Norbert Krause 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 187 KB

## Abstract We report the first example of a tandem kinetic resolution/cycloisomerization of racemic allenic acetates in the presence of __Burkholderia cepacia__ lipase (PS Amano SD) and catalytic amounts of chloroauric acid (HAuCl~4~) which affords 2,5‐dihydrofurans, as well as unreacted starting