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ChemInform Abstract: On the Ability of Ruthenium to Stabilize Polynuclear Hexacyanometallate Film Electrodes.

✍ Scribed by Tommaso R. I. Cataldi; Giuseppe E. De Benedetto

Publisher: John Wiley and Sons
Year: 2010
Weight: 26 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199908018

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✦ Synopsis

On the Ability of Ruthenium to Stabilize Polynuclear Hexacyanometallate Film Electrodes.

-The production of extremely stable Ru-modified inorganic film electrodes is presented. The prussian blue analogues In(III)-, Ni(II)-, Co(II)-hexacyanoferrate and Fe(III)-hexacyanoruthenate are investigated. The process includes electrochemical film deposition and subsequent voltammetric conditioning in a Ru(II)-containing solution at pH 2. The incorporation of Ru seems to impart an extensive crosslinking between hydrate microparticles through dinuclear [Fe, Ru] oxo and cyanide bridges.

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