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ChemInform Abstract: O-Methoxycarbonyl Cyanohydrin as a New Protective Group for Carbonyls.

โœ Scribed by David Berthiaume; Donald Poirier

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Unexpected Formatio
ChemInform Abstract: Unexpected Formation of O-Methoxycarbonyl Cyanohydrin Showing Potential as a Protective Group of Ketones.
โœ Donald Poirier; David Berthiaume; Roch P. Boivin ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB

Unexpected Formation of O-Methoxycarbonyl Cyanohydrin Showing Potential as a Protective Group of Ketones. -Methyl cyanoformate (II) readily reacts with ketones (I) and (IV) in the presence of an amine base to yield O-methoxycarbonyl cyanohydrins. As easy hydrolysis of these cyanohydrins [cf. (V)] w