The reaction of benzenediazonium carboxylate with chloroform in refluxing tetrahydrofuran afforded 5,5,5-trichloropentyl phenyl ether in 61% yield along with benzoic acid (7%). When dichloroacetonitrile was used as a reactant, 5,5-dichloro-5-cyanopentyl phenyl ether was obtained in 65% yield. Reacti
✦ LIBER ✦
ChemInform Abstract: Novel Tandem Reaction of Benzyne with Cyclic Ethers and Active Methines: Synthesis of ω-Trichloroalkyl Phenyl Ethers.
✍ Scribed by Kentaro Okuma; Yuta Fukuzaki; Akiko Nojima; Kosei Shioji; Yoshinobu Yokomori
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 22 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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