ChemInform Abstract: Nickel-Catalyzed Cross-Couplings of Cyclohexenyl Phosphate and Arylboronic Acids.
β Scribed by Yang Nan; Zhen Yang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
## Abstract A variety of unsymmetrical alkynes (III) is readily prepared by a highly efficient Pd(OβAc)~2~βcatalyzed decarboxylative crossβcoupling of boronic acids (I) with acids (II) in the presence of Ag~2~O as oxidant.
Synthesis of Biaryls via a Nickel(0)-Catalyzed Cross-Coupling Reaction of Chloroarenes with Arylboronic Acids. -Optimized conditions are found for coupling of a wide range of chloroarenes with various functionalized arylboronic acids using K 3 PO 4 as base and dioxane or benzene as solvent. Nickel(0